Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60162694%3AG44__%2F08%3A00001927" target="_blank" >RIV/60162694:G44__/08:00001927 - isvavai.cz</a>

Alternative codes found

RIV/61989592:15310/08:00009945

Result on the web

—

DOI - Digital Object Identifier

—

Result language

angličtina

Original language name

Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands

Original language description

A series of planar Ni(II) dithiolenes derived from maleonitriledithiole (mnt), benzene-1,2-dithiole (bdt) and 1-toluene-3,4-dithiole (tdt) with bidentate N,N-ligands (bpyĽ2,20-bipyridine; phenĽ1,10-phenanthroline, nphenĽ5-nitro-1,10-phenanthroline) of the [Ni(N,N)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(phen)(bdt)] confirmed a planar geometry of NiN2S2. Possible practical applications such as use for vulcanization catalytic agents and for their anticholinesterase activity were evaluated.

Czech name

Planární Ni(II) 1,2-dithioleny obsahující bidentátní N-donorové ligandy

Czech description

Serie planárních Ni(II) dithiolenů odvozených od maleonitriledithiole (mnt), benzene-1,2-dithiole (bdt) and 1-toluene-3,4-dithiole (tdt) s bidentátními N,N-ligandy (bpyĽ2,20-bipyridin; phenĽ1,10-fenanthrolin, nfenĽ5-nitro-1,10-fenanthrolin) od [Ni(N,N)(dithiol)] typu byly syntetizovány. Sloučeniny byly charakterizovány elementární analýzou, IR a elektronová spektroskopie, magnetochemické a konduktivitní měření. Monokrystalová rentgrnová analyza [Ni(phen)(bdt)] potvrdila planární geometrii NiN2S2. Možnépraktické aplikace jako užití jakožto katalytické činidlo pro vulkanizaci či látka s anticholinesterázovou aktivitou byly zhodnoceny.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

FP - Other medical fields

OECD FORD branch

—

Project

<a href="/en/project/ME%20865" target="_blank" >ME 865: Countermeasure against chemical terrorism - development of new antidotes against nerve agents</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2008

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Coordination Chemistry

ISSN

0095-8972

e-ISSN

—

Volume of the periodical

61

Issue of the periodical within the volume

22

Country of publishing house

US - UNITED STATES

Number of pages

9

Pages from-to

—

UT code for WoS article

000260213000001

EID of the result in the Scopus database

—