Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F09%3A00010156" target="_blank" >RIV/61989592:15310/09:00010156 - isvavai.cz</a>

Alternative codes found

RIV/60162694:G44__/09:00002172

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands

Original language description

A series of planar Ni(II) dithiolenes derived of maleonitriledithiol (mnt), benzene-1,2-dithiol (bdt) and toluene-3,4-dithiol (tdt) with bidentate P,P-ligands (dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino)propane, dppb = 1,4-bis(diphenylphosphino)butane, dpppn = 1,5-bis(diphenylphosphino)pentane) of the [Ni(P,P)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical, conductivity measurements and thermal analysis. Single crystal X-ray analysis of [Ni(dpppn)(mnt)] confirmed a planar geometry of NiP2S2 chromophore. Possible practical applications such as use of these compounds for vulcanization accelerators and their anticholinesterase activity were evaluated.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

28

Issue of the periodical within the volume

16

Country of publishing house

GB - UNITED KINGDOM

Number of pages

5

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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