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COBALT AND NICKEL COMPLEXES WITH MALEONITRILEDITHIOLATE AND SELECTED N,P-LIGANDS

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F02%3A00001529" target="_blank" >RIV/61989592:15310/02:00001529 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    COBALT AND NICKEL COMPLEXES WITH MALEONITRILEDITHIOLATE AND SELECTED N,P-LIGANDS

  • Original language description

    The new complex compounds of composition [Ni(en)2(mnt)] (I), [Ni(1,2-dap)2 (mnt)].H2O (II), [Ni(n-phen)(mnt)] (III), [Ni2(4,4#-bpy)4(mnt)2Cl(H2O)2].2H2O (IV), [Ni(dpp)(mnt)].H2O (V); [Co(phen)(mnt)].H2O (VI), [Co(dppe)(mnt)].2H2O (VII) and (Me3PhN)2[Ni(mnt)2] (VIII) (en = ethylenediamine, 1,2-dap = 1,2-diaminopropane, n-phen = 5-nitro-1,10-phenanthroline, bpy = bipyridine, mnt2# = maleonitriledithiolate, dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino) propane, Me3PhN+ = trimethylphenylammonium) have been synthesized and studied by common physico-chemical measurements. For compound VIII, the X-ray structure was solved, which confirms the nearly square coordination around the central atom in the NiS4 chromophore.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2002

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium, Chemica

  • ISSN

    0232-0061

  • e-ISSN

  • Volume of the periodical

    41

  • Issue of the periodical within the volume

    N

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    9

  • Pages from-to

    17-25

  • UT code for WoS article

  • EID of the result in the Scopus database