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Comparative study of nucleophilic efficacy of pralidoxime towards phosphorus, sulphur and thiophosphorus based esters

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60162694%3AG44__%2F09%3A00002171" target="_blank" >RIV/60162694:G44__/09:00002171 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Comparative study of nucleophilic efficacy of pralidoxime towards phosphorus, sulphur and thiophosphorus based esters

  • Original language description

    Nucleophilic substitution reaction of p-nitrophenyldiphenyl phosphate, p-nitrophenyl p- toluene sulfonate and insecticide fenitrothion with pralidoxime have been studied at 27oC in the presence of different cationic surfactants. Micellar rate enhancements increase as the cationic head group is made less polar. The order of cleavage of different electrophilic centre by pralidoxime is P=O > S=O > P=S.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    FP - Other medical fields

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/OVUOFVZ200803" target="_blank" >OVUOFVZ200803: Development of novel decontaminants and disinfectants of skin based on micellar compounds</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Reaction Kinetics and Catalysis Letters

  • ISSN

    0133-1736

  • e-ISSN

  • Volume of the periodical

    98

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    HU - HUNGARY

  • Number of pages

    7

  • Pages from-to

  • UT code for WoS article

    000270190100012

  • EID of the result in the Scopus database