The transfer of Ni II- 1,10-phenanthroline complexes across the water / 1,2-dichlorethane interface

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60162694%3A_____%2F99%3A02000013" target="_blank" >RIV/60162694:_____/99:02000013 - isvavai.cz</a>

Alternative codes found

RIV/60162694:G14__/99:02000013

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

The transfer of Ni II- 1,10-phenanthroline complexes across the water / 1,2-dichlorethane interface

Original language description

From the extraction measurements, the equilibrium distribution constant Kd(L) for the electroneutral ligand 1,10-phenanthroline between the 1,2-dichlorethane and aqueos phases has been determined in the form log Kd(L)=1,95, where L represents the ligand.Using known thermodynamic parameters and general relations, stability constants of the metal chelate complexes [Ni(phen)]2+, [Ni(phen)2]2+ a [Ni(phen)3]2+ (phen=1,10-phenantroline) in 1,2-dichlorethane saturated with water have been evaluated. It has been found that the stability constants determined in this medium are essentially higher than the corresponding stability constants of these complexes in water.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

KA - Militarism

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

1999

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Models in Chemistry

ISSN

1217_8969/99

e-ISSN

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Volume of the periodical

136

Issue of the periodical within the volume

3

Country of publishing house

IE - IRELAND

Number of pages

4

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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