Rhodium complexes with perfluoroalkyl-substituted cyclopentadienyl ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F01%3A00003994" target="_blank" >RIV/60461373:22310/01:00003994 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Rhodium complexes with perfluoroalkyl-substituted cyclopentadienyl ligands

Original language description

Mixtures of isomers of (perfluoroalkyl)tetramethylcyclopenta-1,3-dienes (CH3)4C5H(CF2)nCF3 (n = 3, 5, 7, 9) were synthesized as precursors of new cyclopentadienyl ligands for organotransition metal catalysis in fluorous biphase media and characterized bycombination of GC-MS and 13C NMR spectroscopy. Rhodium (III) chloro complexes [Rh{(CH3)4C5(CF2)nCF3}(CO)2] were prepared from the cyclopentadienes and molecular structure of [Rh{(CH3)4C5(CF2)nCF3Cl2]2 was determined by X-ray diffraction. The ligands areelectronically close to the unsubstituted cyclopentadienyl as shown by values of carbonyl stretching frequencies in the carbonyl complexes.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Collection of Czechoslovak Chemical Communications

ISSN

0010-0765

e-ISSN

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Volume of the periodical

66

Issue of the periodical within the volume

2

Country of publishing house

CZ - CZECH REPUBLIC

Number of pages

15

Pages from-to

382-396

UT code for WoS article

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EID of the result in the Scopus database

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