Reactions of 3-chloropentafluoropropene-1,2-oxide with bifunctional nucleophiles: a new route to chlorodifluoromethyl-substituted heterocycles.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F01%3A00004330" target="_blank" >RIV/60461373:22310/01:00004330 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Reactions of 3-chloropentafluoropropene-1,2-oxide with bifunctional nucleophiles: a new route to chlorodifluoromethyl-substituted heterocycles.

Original language description

An optimized preparation of 3-chloropentafluoropropene-1,2-oxide via alkaline peroxide epoxidation of 3-chloropentafluoro-1-propene under phase transfer catalysis conditions is described. The title epoxide was reacted with various bifunctional nitrogen nucleophiles to give five-, six- and seven-membered-ring heterocycles with pendant chlorodifluoromethyl groups. The described methodology represents a novel approach to chlorodifluoromethylated heterocycles.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Fluorine Chemistry

ISSN

0022-1139

e-ISSN

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Volume of the periodical

108

Issue of the periodical within the volume

1

Country of publishing house

BE - BELGIUM

Number of pages

6

Pages from-to

1-5

UT code for WoS article

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EID of the result in the Scopus database

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