Formation of a polymer layer from monomers adsorbed at a liquid vertical bar liquid interface

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F01%3A00004399" target="_blank" >RIV/60461373:22310/01:00004399 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Formation of a polymer layer from monomers adsorbed at a liquid vertical bar liquid interface

Original language description

Polymerization of adsorbed monomers at the water 1,2-dichloroethane interface was studied with a series of surface active derivatives of pyrrole. Polymerization was induced by an electron transfer reaction between a monomer dissolved in the organic phaseand Ce(SO)4 dissolved in the aqueous phase. The formation of a polymer layer at the interface was monitored by surface tension measurement and by cyclic voltammetry in the presence of transferable ions. It was found that in contrast to a simple adsorbedlayer, an interfacial tension in the presence of a polymer layer becomes independent of the applied potential and that a polymer layer strongly inhibits ion transfer reactions.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Electroanalytical chemistry

ISSN

0022-0728

e-ISSN

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Volume of the periodical

516

Issue of the periodical within the volume

N

Country of publishing house

BE - BELGIUM

Number of pages

7

Pages from-to

103-109

UT code for WoS article

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EID of the result in the Scopus database

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