Inhibition of Ion Transfer Reactions by Compact Layers at a Liquid/liquid Interface.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020005" target="_blank" >RIV/61388955:_____/02:54020005 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Inhibition of Ion Transfer Reactions by Compact Layers at a Liquid/liquid Interface.

Original language description

It is demonstrated that adsorbed layers of surface active compounds dissolved in organic phase can be stabilized by a chemical reaction resulting in oxidation of adsorbed monomers by a redox couple dissolved in water. Oxidation of the adsorbed monomer leads to the formation of a compact polymer layer. This formation can be monitored by surface tension measurement and by cyclic voltammetry in the presence of transferable ions. In contrast to a simple adsorbed layer, interfacial tension in the presence ofa polymer layer becomes almost independent of the applied potential and the formed polymer layer strongly inhibits ion transfer reactions.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F00%2F0636" target="_blank" >GA203/00/0636: Formation and investigation of compact layers at liquid/liquid interfaces</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2002

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Analytical Sciences

ISSN

0910-6340

e-ISSN

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Volume of the periodical

17

Issue of the periodical within the volume

Supplement

Country of publishing house

JP - JAPAN

Number of pages

3

Pages from-to

325-327

UT code for WoS article

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EID of the result in the Scopus database

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