Reaction of iron aminocarbene complexes with electronically deficient alkenes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F01%3A00004651" target="_blank" >RIV/60461373:22310/01:00004651 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Reaction of iron aminocarbene complexes with electronically deficient alkenes

Original language description

Thermal reaction of iron aminocarbene complexes bearing aromatic substituent (CO)4Fe=C(Ar)N(CH3)2 with methyl acrylate, acrylonitrile and methyl vinyl ketone furnishes 1,4-dicarbonyl compounds ŻŻ formal products of Michael addition of an acyl anion and the alkene. Nonactivated, di- and trisubstituted alkenes are unreactive under the same conditions.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F00%2F1240" target="_blank" >GA203/00/1240: New sterically hindered and unsaturated Fischer carbene complexes of chromium and iron: physico-chemical properties and reactivity</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal Organomet.Chem.

ISSN

0022-328X

e-ISSN

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Volume of the periodical

617

Issue of the periodical within the volume

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Country of publishing house

BE - BELGIUM

Number of pages

4

Pages from-to

329-333

UT code for WoS article

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EID of the result in the Scopus database

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