CB11H10- and Related Carborenes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F20%3A00532266" target="_blank" >RIV/61388963:_____/20:00532266 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acs.inorgchem.0c01557" target="_blank" >https://doi.org/10.1021/acs.inorgchem.0c01557</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.0c01557" target="_blank" >10.1021/acs.inorgchem.0c01557</a>
Alternative languages
Result language
angličtina
Original language name
CB11H10- and Related Carborenes
Original language description
Starting with HOOC-CB11Me11- or CB11Me12- as the starting material, collision-induced dissociation has produced a series of methylated analogs of didehydro-closo-carbadodecaborane anions by sequential losses of up to 5 equiv of ethylene. These reactive intermediates are carborane analogues of doubly pyramidalized alkenes and, more distantly, arynes. Density functional theory calculations have been used to develop a proposal for the mechanism of the unusual formation of ethylene from the carborane methyl substituents.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
59
Issue of the periodical within the volume
17
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
12453-12460
UT code for WoS article
000570979900065
EID of the result in the Scopus database
2-s2.0-85090478909