Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F19%3A00505383" target="_blank" >RIV/61389013:_____/19:00505383 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11110/19:10403391 RIV/00216208:11310/19:10403391
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2019/PY/C9PY00518H#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2019/PY/C9PY00518H#!divAbstract</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9py00518h" target="_blank" >10.1039/c9py00518h</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system
Original language description
Amphiphilic triblock terpolymers have attractive applications in the preparation of nanoparticles with controlled morphology. An additional level of morphology control can be provided by reactive blocks, whose interactions with the solvent vary under different stimuli. In this work, we synthesized a triblock terpolymer (poly(acrylic acid)-b-poly(4-hydroxystyrene)-b-poly{1-[4-(1-methyl-1,2-dicarba-closo-dodecaborane-2-yl methyl)-phenyl]ethylene}) (PAA-b-PHS-b-PSC) containing carboranes as pendant groups by reversible addition fragmentation chain transfer (RAFT) polymerization and subsequently studied its behavior in aqueous solution. Once the nanoparticles were formed, the solubility of the second and third blocks was changed via pH and CsF reactions, respectively. The resulting micelles work as an ON/OFF system, using changes in fluorescence intensity at different pH values.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10404 - Polymer science
Result continuities
Project
<a href="/en/project/GJ17-00289Y" target="_blank" >GJ17-00289Y: Sugar and pH-responsive multicompartment nano-assemblies for dual-drug solubilization and delivery</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polymer Chemistry
ISSN
1759-9954
e-ISSN
—
Volume of the periodical
10
Issue of the periodical within the volume
22
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
2774-2780
UT code for WoS article
000470708700002
EID of the result in the Scopus database
2-s2.0-85066941572