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Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F19%3A00505383" target="_blank" >RIV/61389013:_____/19:00505383 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11110/19:10403391 RIV/00216208:11310/19:10403391

  • Result on the web

    <a href="https://pubs.rsc.org/en/content/articlelanding/2019/PY/C9PY00518H#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2019/PY/C9PY00518H#!divAbstract</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c9py00518h" target="_blank" >10.1039/c9py00518h</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system

  • Original language description

    Amphiphilic triblock terpolymers have attractive applications in the preparation of nanoparticles with controlled morphology. An additional level of morphology control can be provided by reactive blocks, whose interactions with the solvent vary under different stimuli. In this work, we synthesized a triblock terpolymer (poly(acrylic acid)-b-poly(4-hydroxystyrene)-b-poly{1-[4-(1-methyl-1,2-dicarba-closo-dodecaborane-2-yl methyl)-phenyl]ethylene}) (PAA-b-PHS-b-PSC) containing carboranes as pendant groups by reversible addition fragmentation chain transfer (RAFT) polymerization and subsequently studied its behavior in aqueous solution. Once the nanoparticles were formed, the solubility of the second and third blocks was changed via pH and CsF reactions, respectively. The resulting micelles work as an ON/OFF system, using changes in fluorescence intensity at different pH values.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    <a href="/en/project/GJ17-00289Y" target="_blank" >GJ17-00289Y: Sugar and pH-responsive multicompartment nano-assemblies for dual-drug solubilization and delivery</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polymer Chemistry

  • ISSN

    1759-9954

  • e-ISSN

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    22

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    2774-2780

  • UT code for WoS article

    000470708700002

  • EID of the result in the Scopus database

    2-s2.0-85066941572