Reactivity study of tridecafluoro-5-trifluoromethyl-3,5-dioxanon-1-ene in nucleophilic reactions

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F02%3A00006544" target="_blank" >RIV/60461373:22310/02:00006544 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Reactivity study of tridecafluoro-5-trifluoromethyl-3,5-dioxanon-1-ene in nucleophilic reactions

Original language description

A series of nucleophiles were reacted with the title compound, all reactions were completely regioselective with the nucleophilic attack at the terminal carbon atom. Reactions of hydroxy compounds, thiols and cec-amines afforded addition products, whilebutyllithium, tributylphosphane or complex hydrides caused displacement of vinylic fluorine. Diethylamine and piperidine adducts displayed the property to substitute hydroxyl for fluorine.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F01%2F1311" target="_blank" >GA203/01/1311: New generation of compounds for blood substitutes and other medicinal applications</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2002

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal Pharm.Science

ISSN

0022-3549

e-ISSN

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Volume of the periodical

117

Issue of the periodical within the volume

2

Country of publishing house

BE - BELGIUM

Number of pages

11

Pages from-to

149-159

UT code for WoS article

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EID of the result in the Scopus database

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