A novel fluorescent, conducting polymer: Poly[1-(thiophene-2-yl)benzothieno[3,2-b]benzo-thiophene] electrosynthesis, characterization and optical properties.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F06%3A00017574" target="_blank" >RIV/60461373:22310/06:00017574 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
A novel fluorescent, conducting polymer: Poly[1-(thiophene-2-yl)benzothieno[3,2-b]benzo-thiophene] electrosynthesis, characterization and optical properties.
Original language description
Poly[1-(thiophene-2-yl)benzothieno[3,2-b]benzothiophene] (poly-TBTBT) was electrosynthesized on a Pt electrode by anodic oxidation of TBTBT in 0.1M LiClO4 acetonitrile solution and in a micellar medium (water/methanol, 9/91, v/v) containing 0.39M perchloric acid and 0.1M sodium dodecylsulfate (SDS). Films prepared in acetonitrile were thick and electroactive, whereas in micellar medium they were very thin. Poly-TBTBT was characterized by cyclic voltammetry, MALDI-TOF mass spectrometry, IR, and scanningelectron microscopy (SEM). Poly-TBTBT films were essentially constituted of short-chain oligomers (dimer to octamer). The molecular orbital (MO) calculations, carried out on the basis of a radical-cation electropolymerization mechanism, confirmed the spectral results The optical properties, including the electronic absorption and fluorescence spectra, were also examined.
Czech name
Nové fluorescenční vodivé polymery
Czech description
Byly syntetizovány a charakterizovány nové polymery na bázi substituovaných thienoindolů a studována jejich struktura a elektronické a optické vlastnosti.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—
Result continuities
Project
—
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2006
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Synthetic Metals
ISSN
0379-6779
e-ISSN
—
Volume of the periodical
156
Issue of the periodical within the volume
2
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
256-259
UT code for WoS article
—
EID of the result in the Scopus database
—