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Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F08%3A00020375" target="_blank" >RIV/60461373:22310/08:00020375 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media.

  • Original language description

    Electrosynthesis of poly(2-methyl-thieno[3,2-b]benzothiophene) [poly(2-MeTBT)] and poly(3-methyl-thieno[3,2-b]benzothiophene) [poly(3-MeTBT)], was performed by anodic oxidation of 2-MeTBT and 3-MeTBT on Pt electrode in 0.1M LiClO4 acetonitrile solution and in a partially aqueous micellar medium (water/methanol, 9/91, v/v) containing 0.39M perchloric acid and 0.1MSDS (sodium dodecylsulfate). The electrochemical characteristics and FT-IR spectra of 2-MeTBT and 3-MeTBT, as well as their optical propertieswere studied. The corresponding polymers were investigated by cyclic voltammetry, MALDI-TOF, FT-IR, electronic absorption and fluorescence spectroscopy. A theoretical approach based on molecular orbital (MO) calculations and using a radical-cation electropolymerisation mechanism, was proposed for the oligomer structural characterization.

  • Czech name

    Eelektrochemické, spektrální a teoretické studium nových methylthienobenzothiofenů a jejich polymerů

  • Czech description

    Byla studována syntéza, elektropolymerace, optické vlastnosti série nových polymerů odvozených od methylthienobenzothiofenů.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/OC%20176" target="_blank" >OC 176: Novel monomers for liquid crystalline molecular switches</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Synthetic Metals

  • ISSN

    0379-6779

  • e-ISSN

  • Volume of the periodical

    158

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    19

  • Pages from-to

  • UT code for WoS article

    000255107800002

  • EID of the result in the Scopus database