Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F08%3A00020375" target="_blank" >RIV/60461373:22310/08:00020375 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media.
Original language description
Electrosynthesis of poly(2-methyl-thieno[3,2-b]benzothiophene) [poly(2-MeTBT)] and poly(3-methyl-thieno[3,2-b]benzothiophene) [poly(3-MeTBT)], was performed by anodic oxidation of 2-MeTBT and 3-MeTBT on Pt electrode in 0.1M LiClO4 acetonitrile solution and in a partially aqueous micellar medium (water/methanol, 9/91, v/v) containing 0.39M perchloric acid and 0.1MSDS (sodium dodecylsulfate). The electrochemical characteristics and FT-IR spectra of 2-MeTBT and 3-MeTBT, as well as their optical propertieswere studied. The corresponding polymers were investigated by cyclic voltammetry, MALDI-TOF, FT-IR, electronic absorption and fluorescence spectroscopy. A theoretical approach based on molecular orbital (MO) calculations and using a radical-cation electropolymerisation mechanism, was proposed for the oligomer structural characterization.
Czech name
Eelektrochemické, spektrální a teoretické studium nových methylthienobenzothiofenů a jejich polymerů
Czech description
Byla studována syntéza, elektropolymerace, optické vlastnosti série nových polymerů odvozených od methylthienobenzothiofenů.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/OC%20176" target="_blank" >OC 176: Novel monomers for liquid crystalline molecular switches</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Synthetic Metals
ISSN
0379-6779
e-ISSN
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Volume of the periodical
158
Issue of the periodical within the volume
1
Country of publishing house
GB - UNITED KINGDOM
Number of pages
19
Pages from-to
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UT code for WoS article
000255107800002
EID of the result in the Scopus database
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