ENANTIOSELECTIVE HYDROGENATION OF C=N DOUBLE BOND BY Ru-TsDPEN CATALYST - SPECTRAL AND DFT INVESTIGATION OF THE MECHANISM

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F10%3A00023637" target="_blank" >RIV/60461373:22310/10:00023637 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
ENANTIOSELECTIVE HYDROGENATION OF C=N DOUBLE BOND BY Ru-TsDPEN CATALYST - SPECTRAL AND DFT INVESTIGATION OF THE MECHANISM
Original language description
Chiral compounds are of key importance for a broad range of life sciences and ne chemical products, particularly for pharmaceuticals and agrochemicals. Catalytic enantioselective synthesis is one of the most important synthetic methods for the manufacturing of chiral compounds. Among these methods catalytic asymmetric hydrogenation plays outstanding role both on laboratory and industrially scale. Nowadays asymmetric hydrogenation of C=N has an important role from the practical point of view. For its hydrogenation are reported two different methods using gaseous hydrogen or phase transfer hydrogenation. The transfer hydrogenation is from the practical point of view very useful method which uses organic sources of hydrogen, e.g. propane-2-ol, formic acid. In 1995, Noyori and coworkers published a paper [1], reporting the TsDPEN-coordinated (TsDPEN = N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) Ru(II) complex (Ru-TsDPEN) to be an excellent catalyst for the asymmetric reduction of ar
Czech name
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Czech description
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Project
<a href="/en/project/GA104%2F09%2F1497" target="_blank" >GA104/09/1497: Study of modern aspects of asymmetric hydrogenation of imines</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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