Interaction of Ionic Liquids Ions with Natural Cyclodextrins
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F11%3A43877198" target="_blank" >RIV/60461373:22310/11:43877198 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/11:43877198
Result on the web
<a href="http://dx.doi.org/10.1021/jp205039g" target="_blank" >http://dx.doi.org/10.1021/jp205039g</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jp205039g" target="_blank" >10.1021/jp205039g</a>
Alternative languages
Result language
angličtina
Original language name
Interaction of Ionic Liquids Ions with Natural Cyclodextrins
Original language description
The interaction of natural alpha-, beta-, and gamma-cyclodextrins (CDs) with 14 hydrophobic ionic moieties of ionic liquids (ILs) was systematically examined in dilute aqueous solutions using isothermal titration microcalorimetry (ITC) and NMR spectroscopy. The studied cationic and anionic moieties involved some recently developed heavily fluorinated structures, as well as some others of common use. To isolate the effect of a given ion, the measurements were performed on salts containing the hydrophobicIL ion in question and a complexation-inactive counterion. Additional ITC experiments on ILs whose both cation and anion can interact appreciably with the CD cavity demonstrated that to resolve the effect of individual ions from such data is generally atricky task and confirmed the superiority of the isolation strategy adopted for the purpose throughout this work. The binding constant, enthalpy and entropy determined at 298.15 K for the 1:1 (ion:CD) inclusion complex formation range in
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN
1520-6106
e-ISSN
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Volume of the periodical
115
Issue of the periodical within the volume
34
Country of publishing house
US - UNITED STATES
Number of pages
13
Pages from-to
10285-10297
UT code for WoS article
000294146200011
EID of the result in the Scopus database
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