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Interaction of Ionic Liquids Ions with Natural Cyclodextrins

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F11%3A43877198" target="_blank" >RIV/60461373:22310/11:43877198 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22340/11:43877198

  • Result on the web

    <a href="http://dx.doi.org/10.1021/jp205039g" target="_blank" >http://dx.doi.org/10.1021/jp205039g</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/jp205039g" target="_blank" >10.1021/jp205039g</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Interaction of Ionic Liquids Ions with Natural Cyclodextrins

  • Original language description

    The interaction of natural alpha-, beta-, and gamma-cyclodextrins (CDs) with 14 hydrophobic ionic moieties of ionic liquids (ILs) was systematically examined in dilute aqueous solutions using isothermal titration microcalorimetry (ITC) and NMR spectroscopy. The studied cationic and anionic moieties involved some recently developed heavily fluorinated structures, as well as some others of common use. To isolate the effect of a given ion, the measurements were performed on salts containing the hydrophobicIL ion in question and a complexation-inactive counterion. Additional ITC experiments on ILs whose both cation and anion can interact appreciably with the CD cavity demonstrated that to resolve the effect of individual ions from such data is generally atricky task and confirmed the superiority of the isolation strategy adopted for the purpose throughout this work. The binding constant, enthalpy and entropy determined at 298.15 K for the 1:1 (ion:CD) inclusion complex formation range in

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    JOURNAL OF PHYSICAL CHEMISTRY B

  • ISSN

    1520-6106

  • e-ISSN

  • Volume of the periodical

    115

  • Issue of the periodical within the volume

    34

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    13

  • Pages from-to

    10285-10297

  • UT code for WoS article

    000294146200011

  • EID of the result in the Scopus database