Rearrangement of 4-methyldicyclopentadiene to 2-methyldicyclopentadiene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F11%3A43892034" target="_blank" >RIV/60461373:22310/11:43892034 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Rearrangement of 4-methyldicyclopentadiene to 2-methyldicyclopentadiene
Original language description
It was observed that 4-methyl-endo-3a,4,7,7a-tetrahydro-1H-4,7-methanoindene, when heated at 100°C, isomerizes to a thermodynamically more stable isomer, 2-methyl-endo-3a,4,7,7a-tetrahydro-1H-4,7-methanoindene, through [3,3]-sigmatropic rearrangement. The kinetics of this thermal rearrangement was studied in the liquid phase in the temperature range of 80 - 140°C and kinetic parameters were evaluated.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/FT-TA3%2F079" target="_blank" >FT-TA3/079: *Research of the progressive chemical products based on dicyclopentadiene.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Petroleum and Coal
ISSN
1337-7027
e-ISSN
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Volume of the periodical
53
Issue of the periodical within the volume
3
Country of publishing house
SK - SLOVAKIA
Number of pages
4
Pages from-to
233-237
UT code for WoS article
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EID of the result in the Scopus database
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