Kinetics of Diels-Alder reactions between 1,3-cyclopentadiene and isoprene

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F15%3A43900317" target="_blank" >RIV/60461373:22310/15:43900317 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s11144-015-0913-5" target="_blank" >http://dx.doi.org/10.1007/s11144-015-0913-5</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11144-015-0913-5" target="_blank" >10.1007/s11144-015-0913-5</a>

Result language
angličtina
Original language name
Kinetics of Diels-Alder reactions between 1,3-cyclopentadiene and isoprene
Original language description
The work deals with a detailed study of the kinetics of the cycloaddition reactions between isoprene and cyclopentadiene. The laboratory experiments were carried out in a batch reactor in a cyclohexane solution at different temperatures. Measured concentrations of the reactants and 1:1 Diels-Alder adducts were fitted to the kinetic model. Kinetic parameters for formation of 5 individual isomeric codimers of cyclopentadiene and isoprene were determined. Kinetic measurements gave evidence that 5 methyl-cis-3a,4,7,7a-tetrahydro-1H-indene is formed by two reaction routes: (i) by the Diels-Alder reaction of cyclopentadiene with isoprene in which cyclopentadiene acts as a dienophile, and (ii) by the Cope rearrangement from endo 5-isopropenyl-2-norbornene, the dominant codimer. It depends on the reaction conditions which of them prevails.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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