Kinetics of thermal dimerizations of cyclopentadiene and methylcyclopentadienes and their codimerization

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F10%3A00023339" target="_blank" >RIV/60461373:22310/10:00023339 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Kinetics of thermal dimerizations of cyclopentadiene and methylcyclopentadienes and their codimerization

Original language description

The kinetics of the formation of isomeric dimers and codimers via thermal dimerization and codimerization between cyclopentadiene, 1-methyl-1,3-cyclopentadiene and 2-methyl-1,3-cyclopentadiene were studied. The laboratory experiments were carried out ina batch reactor in a cyclohexane solution at different temperatures. Measured concentrations of the reactants and 1:1 Diels-Alder adducts were fitted to the kinetic model. Kinetic parameters for formation of the individual isomeric products and the summary reactions were determined. The overall rates of cyclopentadiene and methylcyclopentadiene dimerizations and their mutual codimerization were found to be identical throughout the temperature range in which the reactions are kinetically controlled. Thepresence of a methyl group on the cyclopentadiene ring does not decrease the reactivity of the monomer in the Diels-Alder reaction. The reactivities of both methylcyclopentadiene isomers are the same.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CI - Industrial chemistry and chemical engineering

OECD FORD branch

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Project

<a href="/en/project/FT-TA3%2F079" target="_blank" >FT-TA3/079: *Research of the progressive chemical products based on dicyclopentadiene.</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Petroleum and Coal

ISSN

1337-7027

e-ISSN

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Volume of the periodical

2010

Issue of the periodical within the volume

52

Country of publishing house

SK - SLOVAKIA

Number of pages

16

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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