Kinetics of cycloaddition reactions of conjugated C5 dienes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F14%3A43898458" target="_blank" >RIV/60461373:22310/14:43898458 - isvavai.cz</a>
Result on the web
<a href="http://www.vurup.sk/volume-56-2014-issue-4" target="_blank" >http://www.vurup.sk/volume-56-2014-issue-4</a>
DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Kinetics of cycloaddition reactions of conjugated C5 dienes
Original language description
The kinetics of the formation of isomeric dimers and codimers via thermal dimerization and codimerization between 1,3-cyclopentadiene, isoprene, cis-1,3-pentadiene and trans-1,3-pentadiene were studied. The laboratory experiments were carried out in a batch reactor in a cyclohexane solution at different temperatures. Measured concentrations of the reactants and 1:1 Diels-Alder adducts were fitted to the kinetic model. Kinetic parameters for formation of the individual isomeric products and the summary reactions were determined. It was found that the activation energies of dimerizations of acyclic C5 dienes are by 20-40 kJ/mol higher than that of the dimerization of cyclopentadiene, and the activation energies of the formation of codimers of cyclopentadiene with 1,3-pentadienes are higher by 10-20 kJ/mol.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CI - Industrial chemistry and chemical engineering
OECD FORD branch
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Result continuities
Project
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Continuities
O - Projekt operacniho programu
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Petroleum and Coal
ISSN
1337-7027
e-ISSN
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Volume of the periodical
56
Issue of the periodical within the volume
4
Country of publishing house
SK - SLOVAKIA
Number of pages
14
Pages from-to
428-441
UT code for WoS article
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EID of the result in the Scopus database
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