Synthesis and characterisation of a new naphthalene tris-Troger's base derivative-a chiral molecular clip

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43895004" target="_blank" >RIV/60461373:22310/13:43895004 - isvavai.cz</a>

Alternative codes found

RIV/60461373:22340/13:43895004

Result on the web

<a href="http://dx.doi.org/10.1016/j.tetlet.2012.11.035" target="_blank" >http://dx.doi.org/10.1016/j.tetlet.2012.11.035</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.tetlet.2012.11.035" target="_blank" >10.1016/j.tetlet.2012.11.035</a>

Result language

angličtina

Original language name

Synthesis and characterisation of a new naphthalene tris-Troger's base derivative-a chiral molecular clip

Original language description

Serial tris-Troger's base derivatives (trisTBs) are members of a recently introduced family of chiral molecular clips. Naphthalene tris-Troger's base is prepared via both stepwise and one-pot approaches. All three diastereoisomers are isolated and unambiguously identified, and their NMR spectra, enantioseparation and binding ability are studied. The syn,syn-trisTB diastereoisomer, a molecular clip, is found to be a potential molecular receptor of electron-deficient cyanobenzenes. For the first time, racemic syn,syn-trisTB is resolved via preparative HPLC (chiral column) and the absolute configurations are assigned by comparison of experimental and calculated ECD spectra. General dependencies on the oligoTB stability in acid media and potential anion binding are suggested.

Czech name

—

Czech description

—

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CB - Analytical chemistry, separation

OECD FORD branch

—

Project

<a href="/en/project/GA203%2F08%2F1445" target="_blank" >GA203/08/1445: Functional Molecular Tweezers Based on Bis Tröger's Bases</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Tetrahedron Letters

ISSN

0040-4039

e-ISSN

—

Volume of the periodical

54

Issue of the periodical within the volume

4

Country of publishing house

GB - UNITED KINGDOM

Number of pages

4

Pages from-to

308-311

UT code for WoS article

000314388200007

EID of the result in the Scopus database

—