Determination of relative configuration of symmetrical bis-Troger's base derivatives
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F11%3A43871494" target="_blank" >RIV/60461373:22340/11:43871494 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/11:00360783
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2011.04.018" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2011.04.018</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2011.04.018" target="_blank" >10.1016/j.molstruc.2011.04.018</a>
Alternative languages
Result language
angličtina
Original language name
Determination of relative configuration of symmetrical bis-Troger's base derivatives
Original language description
Determination of the molecular covalent structure based on spectral analyses is almost routine; however, estimation of stereostructure is still challenging, particularly in case of symmetrical molecules. In this study, various spectral (NMR, IR and Raman) markers revealing relative configuration (syn and anti) of bis-Troger's base diastereoisomers are identified. Differences in diastereoisomers (1)H chemical shifts seem to be most useful, as they can be interpreted by computations. Vibrational spectra of syn and anti diastereoisomers exhibited systematic differences, too. The relative configuration can be also predicted based on retention on silica, and unambiguously confirmed via chromatographic analysis on a chiral stationary phase.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Structure
ISSN
0022-2860
e-ISSN
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Volume of the periodical
996
Issue of the periodical within the volume
1
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
69-74
UT code for WoS article
000292579800011
EID of the result in the Scopus database
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