Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(n6-p-cymene)TsDPEN].

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43895580" target="_blank" >RIV/60461373:22310/13:43895580 - isvavai.cz</a>
Result on the web
<a href="http://link.springer.com/article/10.1007%2Fs10562-013-0996-4" target="_blank" >http://link.springer.com/article/10.1007%2Fs10562-013-0996-4</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10562-013-0996-4" target="_blank" >10.1007/s10562-013-0996-4</a>

Result language
angličtina
Original language name
Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(n6-p-cymene)TsDPEN].
Original language description
The asymmetric transfer hydrogenation of five dihydroisoquinolines (DHIQs) was studied by NMR spectroscopy. The DHIQs differed by substitution with methoxy groups, which had a significant effect upon the reaction performance in terms of reaction rate andenantioselectivity. The differences are most probably related to the basicity of DHIQs.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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