Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN]

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388971%3A_____%2F13%3A00425867" target="_blank" >RIV/61388971:_____/13:00425867 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s10562-013-0996-4" target="_blank" >http://dx.doi.org/10.1007/s10562-013-0996-4</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10562-013-0996-4" target="_blank" >10.1007/s10562-013-0996-4</a>

Result language
angličtina
Original language name
Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN]
Original language description
The asymmetric transfer hydrogenation of five dihydroisoquinolines (DHIQs) was studied by NMR spectroscopy. The DHIQs differed by substitution with methoxy groups, which had a significant effect upon the reaction performance in terms of reaction rate andenantioselectivity. The differences are most probably related to the basicity of DHIQs.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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