Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F14%3A43897771" target="_blank" >RIV/60461373:22310/14:43897771 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s10934-014-9822-7" target="_blank" >http://dx.doi.org/10.1007/s10934-014-9822-7</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10934-014-9822-7" target="_blank" >10.1007/s10934-014-9822-7</a>
Alternative languages
Result language
angličtina
Original language name
Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials
Original language description
The presented report focuses on the testing of heterogenized methyltrioxorhenium (MTO) in indene epoxidation. A range of mesoporous materials with different SiO2/Al2O3 ratios, namely aluminosilicates type Siral and MCM-41 silica and fumed silica, were used as supports for immobilization of MTO. The tested support materials and prepared catalytic systems exhibited high surface area, well-defined regular structure and narrow pore size distribution of mesopores and therefore represent good quality catalysts for various reactions. The immobilized MTO on various supports was tested for the preparation of 1,2-epoxyindane using two forms of hydrogen peroxide as oxidation agents, namely aqueous solution of hydrogen peroxide and its anhydrous form, urea-hydrogen peroxide. The prepared catalysts were successfully used for the preparation of 1,2-epoxyindane with achieved 100 % selectivities to the desired product at high conversions of indene.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Porous Materials
ISSN
1380-2224
e-ISSN
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Volume of the periodical
21
Issue of the periodical within the volume
5
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
"757:767"
UT code for WoS article
000341840900027
EID of the result in the Scopus database
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