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Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F14%3A43897771" target="_blank" >RIV/60461373:22310/14:43897771 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s10934-014-9822-7" target="_blank" >http://dx.doi.org/10.1007/s10934-014-9822-7</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10934-014-9822-7" target="_blank" >10.1007/s10934-014-9822-7</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials

  • Original language description

    The presented report focuses on the testing of heterogenized methyltrioxorhenium (MTO) in indene epoxidation. A range of mesoporous materials with different SiO2/Al2O3 ratios, namely aluminosilicates type Siral and MCM-41 silica and fumed silica, were used as supports for immobilization of MTO. The tested support materials and prepared catalytic systems exhibited high surface area, well-defined regular structure and narrow pore size distribution of mesopores and therefore represent good quality catalysts for various reactions. The immobilized MTO on various supports was tested for the preparation of 1,2-epoxyindane using two forms of hydrogen peroxide as oxidation agents, namely aqueous solution of hydrogen peroxide and its anhydrous form, urea-hydrogen peroxide. The prepared catalysts were successfully used for the preparation of 1,2-epoxyindane with achieved 100 % selectivities to the desired product at high conversions of indene.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Porous Materials

  • ISSN

    1380-2224

  • e-ISSN

  • Volume of the periodical

    21

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    "757:767"

  • UT code for WoS article

    000341840900027

  • EID of the result in the Scopus database