Indene epoxidation over immobilized methyltrioxorhenium on silicate and aluminosilicate materials

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F13%3AMSMT18CL" target="_blank" >RIV/62243136:_____/13:MSMT18CL - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—

Result language
angličtina
Original language name
Indene epoxidation over immobilized methyltrioxorhenium on silicate and aluminosilicate materials
Original language description
The range of mesoporous materials with different SiO2/Al2O3 ratio, namely aluminosilicates type Siral, silica and MCM-41, were used as supports for immobilization of MTO. The tested support materials and prepared catalytic systems exhibited high surfacearea, well-defined regular structure and narrow pore size distribution of mesopores and therefore represent excellent catalysts for various reactions. The immobilized MTO on various supports was tested for preparation of 1,2-epoxyindane using two forms of hydrogen peroxide as oxidation agents, namely aqueous solution of hydrogen peroxide and its anhydrous form, urea-hydrogen peroxide (UHP). The catalysts were successfully used for preparation of 1,2-epoxyindane with achieved 100 % selectivities to desired product at high conversions of indene.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/ED2.1.00%2F03.0071" target="_blank" >ED2.1.00/03.0071: Unipetrol Centre of Research and Education</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)