Methoxyaryl substituted aluminum ketiminate complexes and its activity in ring opening polymerization processes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F15%3A43899638" target="_blank" >RIV/60461373:22310/15:43899638 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/15:39900092
Result on the web
<a href="http://dx.doi.org/10.1016/j.inoche.2015.03.039" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2015.03.039</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2015.03.039" target="_blank" >10.1016/j.inoche.2015.03.039</a>

Result language
angličtina
Original language name
Methoxyaryl substituted aluminum ketiminate complexes and its activity in ring opening polymerization processes
Original language description
The synthesis of dimethyl aluminum (LoAlMe2) and chloromethyl aluminum (LoAlMeCl) complexes containing ketiminate ligand [(2-MeO)C6H4]N(H)C(Me) = CHC(Me) = O (LoH) is reported along with the preparation of Lo3Al from LoH and LiAlH4, and ionic [Lo'Al(thf)3]I from LoAlMe2 and I2. In the later complex the pseudooctahedral geometry of the aluminum ion by terdentate ligand {[(2-O)C6H4]NC(Me) = CHC(Me) = O}2 MINUS SIGN (Lo'), originated from Lo ligand by the methyl group abstraction, and three THF molecules are observed. Structures of these complexes were determined by X-ray techniques. The activity of LoAlMe2 and LoAlMeCl as initiators of ring opening polymerization of ?-caprolactone, trimethylene carbonate and l-lactide, and (co)polymerization of cyclohexene oxide and carbon dioxide was studied.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP106%2F10%2F0924" target="_blank" >GAP106/10/0924: The electron deficient transition metal complexes containing bifunctional beta-diketiminate and cyclopentadienyl ligands ? design of new catalysts.</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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