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Effect of addition of a second metal in Mo/ZSM-5 catalyst for methane aromatization reaction under elevated pressures

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F15%3A43900776" target="_blank" >RIV/60461373:22310/15:43900776 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388955:_____/15:00462409

  • Result on the web

    <a href="http://ac.els-cdn.com/S0920586115001443/1-s2.0-S0920586115001443-main.pdf?_tid=5df70f00-df3e-11e5-89a7-00000aab0f26&acdnat=1456789646_297c978098cf6df60b6c223f22f2d819" target="_blank" >http://ac.els-cdn.com/S0920586115001443/1-s2.0-S0920586115001443-main.pdf?_tid=5df70f00-df3e-11e5-89a7-00000aab0f26&acdnat=1456789646_297c978098cf6df60b6c223f22f2d819</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.cattod.2015.02.035" target="_blank" >10.1016/j.cattod.2015.02.035</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effect of addition of a second metal in Mo/ZSM-5 catalyst for methane aromatization reaction under elevated pressures

  • Original language description

    Non-oxidative methane dehydro-aromatization (MDA) over transitional metal-doped zeolites (i.e. ZSM-5) has a potential to be an alternative for methane transformation processes to higher hydrocarbons. Despite of systematic studies of the effects of the catalyst composition, preparation procedure, pretreatment, and the reaction conditions systematically followed since the pioneering works of the Chinese group in 1993, the suppression of fast deactivation of catalyst by coke deposition was still not solvedsuccessfully. In the present work the long-term MDA experiments at 973 K and elevated pressures up to 600 kPa were carried out with metal-doped Mo/ZSM-5 catalysts. Several Mo-based catalysts doped with various amount of Co, Mn, and Ce were prepared andtested in the MDA reaction. Experimental results are presented in terms of profiles of methane conversion as well as ethylene, benzene, and toluene concentrations as a function of time on stream, accompanied by the TGA analysis of the cok

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Catalysis Today

  • ISSN

    0920-5861

  • e-ISSN

  • Volume of the periodical

    256

  • Issue of the periodical within the volume

    1 November 2015

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    6

  • Pages from-to

    269-275

  • UT code for WoS article

    000360657000007

  • EID of the result in the Scopus database