Fluorination of Black Phosphorus — Will Black Phosphorus Burn Down in the Elemental Fluorine?
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43915739" target="_blank" >RIV/60461373:22310/18:43915739 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/adfm.201801438" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/adfm.201801438</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adfm.201801438" target="_blank" >10.1002/adfm.201801438</a>
Alternative languages
Result language
angličtina
Original language name
Fluorination of Black Phosphorus — Will Black Phosphorus Burn Down in the Elemental Fluorine?
Original language description
Black phosphorus (BP) represents a promising tunable bandgap alternative to graphene and other 2D materials in the field of semiconductors. However, its reactivity toward covalent modification of its surface (as a key to its bandgap adjustment) is scarcely reported. Here a method of covalent modification of BP involving reaction with fluorine is reported. Other allotropes of phosphorus are known to react violently with fluorine resulting in its complete burning down and formation of gaseous phosphorus pentafluoride. The results of our fluorination experiments conducted in analogy to the procedures used for fluorination of graphene indicate a successful binding of fluorine to BP. This route of modification of BP opens new possible ways toward covalent modification of the surface of this promising material.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA17-11456S" target="_blank" >GA17-11456S: Layered transition metal dichalcogenides nanostructures for electrocatalysis</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Advanced Functional Materials
ISSN
1616-301X
e-ISSN
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Volume of the periodical
28
Issue of the periodical within the volume
35
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
1801438
UT code for WoS article
000442731200005
EID of the result in the Scopus database
2-s2.0-85050396378