Products of Degradation of Black Phosphorus in Protic Solvents
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43915740" target="_blank" >RIV/60461373:22310/18:43915740 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/pdf/10.1021/acsnano.8b03740" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acsnano.8b03740</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsnano.8b03740" target="_blank" >10.1021/acsnano.8b03740</a>
Alternative languages
Result language
angličtina
Original language name
Products of Degradation of Black Phosphorus in Protic Solvents
Original language description
Deterioration of the surface of black phosphorus (BP) caused by ambient atmosphere is an undesired process, limiting broader use of BP in many areas. The mechanism of BP degradation was explained theoretically, and the oxidized materials were thoroughly characterized experimentally. However, the surface analysis techniques introduce only a limited insight into the real state of the material. Here, we report a thorough analysis of the composition of mixtures obtained after a prolonged exposure of suspensions of BP to atmospheric oxygen with the aim to further disclosure the processes involved in the decomposition process. The results are compared with the predicted structures of the oxidized material and confirm the results of the theoretical calculations. The comparison of reactivity of BP with reactivity of white phosphorus under similar conditions concludes a similar distribution of the products in both cases.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA16-05167S" target="_blank" >GA16-05167S: Ion beam modifications of graphene based structures</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Nano
ISSN
1936-0851
e-ISSN
—
Volume of the periodical
12
Issue of the periodical within the volume
8
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
8390-8396
UT code for WoS article
000443525600090
EID of the result in the Scopus database
2-s2.0-85054468353