Covalent functionalization of exfoliated arsenic with chlorocarbene

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43915747" target="_blank" >RIV/60461373:22310/18:43915747 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/ange.201809341" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/ange.201809341</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201809341" target="_blank" >10.1002/anie.201809341</a>

Result language
angličtina
Original language name
Covalent functionalization of exfoliated arsenic with chlorocarbene
Original language description
Few-layer and monolayer arsenic (arsenene) materials have been attracting great attention mainly from a theoretical perspective. Chemical modification of these materials would expand significantly the range of their applications. Here, we describe a chlorocarbene-mediated modification of exfoliated layered arsenic materials. Carbene-based species are highly reactive and offer further possibilities of functionalization. Our approach for modifying the arsenic surface by chlorocarbene generated from organolithium and dichloromethane resulted in a large surface coverage and a highly luminescent functionalized material, opening the door for its application in modern optoelectronic devices.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA17-11456S" target="_blank" >GA17-11456S: Layered transition metal dichalcogenides nanostructures for electrocatalysis</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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