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Coordination chemistry of 2D and layered gray arsenic: photochemical functionalization with chromium hexacarbonyl

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43918136" target="_blank" >RIV/60461373:22310/19:43918136 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216305:26620/19:PU133215

  • Result on the web

    <a href="https://www.nature.com/articles/s41427-019-0142-x" target="_blank" >https://www.nature.com/articles/s41427-019-0142-x</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1038/s41427-019-0142-x" target="_blank" >10.1038/s41427-019-0142-x</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Coordination chemistry of 2D and layered gray arsenic: photochemical functionalization with chromium hexacarbonyl

  • Original language description

    The functionalization of layered materials is one of the current challenges in material science. Exfoliated rhombohedral (gray) arsenic represents a promising layered material for the fabrication of electronic devices and sensors; however, synthetic protocols for tuning its properties or protecting the surface by covalent functionalization are not known. In this communication, we present its covalent functionalization accompanied by the exfoliation of rhombohedral arsenic in the presence of ultraviolet light irradiation and chromium hexacarbonyl. During this modification, the arsenic atoms act as ligands to the chromium metal center. We believe that this study provides a promising approach for the modification of rhombohedral few-layer arsenene and enables its application in various fields, including electronic devices, sensors, and energy devices.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    NPG ASIA MATERIALS

  • ISSN

    1884-4049

  • e-ISSN

  • Volume of the periodical

    11

  • Issue of the periodical within the volume

    AUG 23 2019

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

  • UT code for WoS article

    000483900600001

  • EID of the result in the Scopus database

    2-s2.0-85071334455