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Antimony Chalcogenide van der Waals Nanostructures for Energy Conversion and Storage

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43918141" target="_blank" >RIV/60461373:22310/19:43918141 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216305:26620/19:PU134072

  • Result on the web

    <a href="https://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.9b04415" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.9b04415</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acssuschemeng.9b04415" target="_blank" >10.1021/acssuschemeng.9b04415</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Antimony Chalcogenide van der Waals Nanostructures for Energy Conversion and Storage

  • Original language description

    Among van der Waals nanomaterials, topological insulators such as antimony chalcogenides (Sb2X3, X = S, Se, Te) have interesting thermoelectric and optical properties. Expressly, Sb2S3 is regarded as a favorable anode material for batteries owing to its predicted specific capacity. Both Sb2S3 and Sb2Se3 have an isomorphous tubular one-dimensional (1D) crystal structure, whereas Sb2Te3 has a two-dimensional (2D) layered structure. The synthesized bulk crystals of Sb2X3 were submitted to liquid-phase shear force exfoliation. The 1D and 2D Sb2X3 undergo downsizing processes, also complemented by delamination, to submicron sheets and with an average thickness down to 37 nm. The inherent electrochemical and heterogeneous electron transfer properties of the materials were first studied. Exfoliated Sb2S3 had the best performance for the hydrogen evolution reaction in a wide pH range, with improvements in the overpotential of up to 500 mV, with respect to the starting material. Specifically, in acidic media, exfoliated Sb2S3 also has a good stability for multiple cycles and continuous operation. Likewise, exfoliated Sb2S3 had the highest gravimetric capacitive behavior in alkaline solution.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS Sustainable Chemistry &amp; Engineering

  • ISSN

    2168-0485

  • e-ISSN

  • Volume of the periodical

    7

  • Issue of the periodical within the volume

    18

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    15790-15798

  • UT code for WoS article

    000486565900069

  • EID of the result in the Scopus database

    2-s2.0-85072716159