Modified Leach Residues from Processing Deep-Sea Nodules as E ective Heavy Metals Adsorbents

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43919442" target="_blank" >RIV/60461373:22310/19:43919442 - isvavai.cz</a>

Result on the web

<a href="https://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=39&SID=C4PJOgi8UHZIDFobRUp&page=1&doc=2" target="_blank" >https://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=39&SID=C4PJOgi8UHZIDFobRUp&page=1&doc=2</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/met9040472" target="_blank" >10.3390/met9040472</a>

Result language

angličtina

Original language name

Modified Leach Residues from Processing Deep-Sea Nodules as E ective Heavy Metals Adsorbents

Original language description

The possible use of leaching residue from leaching deep-sea nodules in SO2/H2SO4/H2O medium as a low-cost adsorbent of heavy metals (Pb(II), Cd(II), Cu(II), Ni(II), Co(II), As(V)) was studied. The leaching residue was found to be an e ective adsorbent for all of the tested elements; however, it was inactive in the solution containing As(V). The chemical activation of adsorbent in 10 vol. % HCl resulted in the greatest improvement of adsorption properties, while the activation in 10 vol. % HNO3 and heat treatment at 250 C did not significantly a ect the sorption characteristics of treated adsorbents compared with the original leaching residue. After HCl activation, the maximal adsorption capacities for lead (12.0 mg/g at pH 5.0 after 1 h), nickel (3.1 mg/g at pH 5.5 after 4 h) and cobalt (2.0 mg/g at pH 5.0 after 2 h) were achieved. Additional mechanical treatment connected with HCl activation provided the highest adsorption capacities for cadmium (11.5 mg/g at pH 4.0) and copper (5.7 mg/g at pH 4.5). Coprecipitation of Fe/Al-based particles on the surface of the leaching residue increased As(V) removal of the adsorbent. Surface coating based on AlIII was extremely effective, causing the increase of the adsorption capacity from 0 with the original leaching residue, to 28.1 mg/g (pH 7.0, 24 min). Kinetics studies showed the rapid progress of adsorption for Pb(II), Cd(II), and As(V) in tens of minutes, while the adsorption of Cu(II), Ni(II) and Co(II) approached a steady state after 2 h.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

20501 - Materials engineering

Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Metals

ISSN

2075-4701

e-ISSN

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Volume of the periodical

9

Issue of the periodical within the volume

4

Country of publishing house

CH - SWITZERLAND

Number of pages

12

Pages from-to

1-12

UT code for WoS article

000467637000089

EID of the result in the Scopus database

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