Plasmon-assisted self-cleaning sensor for the detection of organosulfur compounds in fuels
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43919480" target="_blank" >RIV/60461373:22310/19:43919480 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2019/TC/C9TC03690C#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2019/TC/C9TC03690C#!divAbstract</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9tc03690c" target="_blank" >10.1039/c9tc03690c</a>
Alternative languages
Result language
angličtina
Original language name
Plasmon-assisted self-cleaning sensor for the detection of organosulfur compounds in fuels
Original language description
Monitoring of organosulfur compounds in fuels is an urgent need for the control of their quality. The major deficiencies of common approaches for the determination of sulfur-containing heterocycles, especially dibenzothiophene (DBT) derivatives, are the time and equipment demand, as well as the impossibility of portable measurements. Thus, the reliable and sensitive detection of organosulfur derivatives in fuels, in an expeditious and portative manner, represent an actual challenge. In this work, the advanced design of SERS substrates for the reliable and ultrasensitive detection of DBT derivatives in real samples of biodiesel is proposed. The SERS substrates were created based on the plasmon-polariton supported gold grating, providing effective and reproducible SERS measurements. An additional coating of the gold grating surface with a thin Pt layer facilitates the entrapping of sulfur-containing organic compounds. The created SERS substrates show a low detection limit (10-12 M), high reliability and compatibility with portable Raman spectrometers. Moreover, the possibility to regenerate the SERS substrate via a plasmon-induced reaction in cyclohexene was also demonstrated, providing bright opportunities for sensor re-utilization. © 2019 The Royal Society of Chemistry.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
20501 - Materials engineering
Result continuities
Project
<a href="/en/project/GA18-26170S" target="_blank" >GA18-26170S: Light triggerable p-conjugated polymers for ON/OFF reversible conductivity switching</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Materials Chemistry C
ISSN
2050-7526
e-ISSN
—
Volume of the periodical
7
Issue of the periodical within the volume
45
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
14181-14187
UT code for WoS article
000503215800012
EID of the result in the Scopus database
2-s2.0-85075607518