Solvent Effects in Biomass Processing: α- and β-Pinene Oxide Rearrangements.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43920601" target="_blank" >RIV/60461373:22310/20:43920601 - isvavai.cz</a>
Result on the web
<a href="https://novapublishers.com/shop/solvent-effects-in-chemistry-advances-in-applications-and-research/" target="_blank" >https://novapublishers.com/shop/solvent-effects-in-chemistry-advances-in-applications-and-research/</a>
DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Solvent Effects in Biomass Processing: α- and β-Pinene Oxide Rearrangements.
Original language description
α- and β-Pinenes are compounds naturally occurring in pine resins (or in other conifers) and are the main constituents of turpentine oil. Many important compounds may be derived from pinenes, most of them find their usage in perfume chemistry. Through the oxidation of pinenes, pinene oxides may be prepared. Depending on the reaction conditions, different important products are obtained from the rearrangement of α- or β-pinene oxides. α-Pinene oxide serves as a starting material for the production of campholenic aldehyde (a fragrant compound) or trans-carveol (fragrant and chemotherapeutical properties). Dependently on acid sites present on the catalyst surface, the selectivity may be directed. The chosen solvent may also play the same role in directing the selectivity. Strong basic polar solvents induce the selectivity towards trans-carveol whereas low-basic solvents towards campholenic aldehyde. Similarly, from β-pinene oxide, two types of important compounds may be obtained: myrtenol or myrtanal (serving as fragrances, produced using low basic non-polar solvents) and perillyl alcohol (a compound with interesting biological activity, produced using strong basic solvents). The use of a large of variety of solvents is discussed in this chapter, varying from non-polar low basic solvents (e.g., toluene) to polar strong basic solvents (e.g., DMSO) showing that the properties of different solvents strongly influence the product composition of both studied reactions.
Czech name
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Czech description
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Classification
Type
C - Chapter in a specialist book
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/LO1613" target="_blank" >LO1613: Future materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Book/collection name
Solvent Effects in Chemistry: Advances in Applications and Research
ISBN
978-1-5361-8226-2
Number of pages of the result
32
Pages from-to
189-220
Number of pages of the book
285
Publisher name
Nova Science Publishers, Inc.
Place of publication
New York
UT code for WoS chapter
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