Formation of trisubstituted buta-1,3-dienes and alpha,beta-unsaturated ketonesviathe reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43921716" target="_blank" >RIV/60461373:22310/20:43921716 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlepdf/2020/ra/d0ra07472a" target="_blank" >https://pubs.rsc.org/en/content/articlepdf/2020/ra/d0ra07472a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d0ra07472a" target="_blank" >10.1039/d0ra07472a</a>
Alternative languages
Result language
angličtina
Original language name
Formation of trisubstituted buta-1,3-dienes and alpha,beta-unsaturated ketonesviathe reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents
Original language description
We studied the reactions of vinyl phosphates and vinyl phosphordiamidates containing an ester functional group with organometallic reagents. We found that the functionalized vinyl phosphates were smoothly converted into tri- and tetrasubstituted buta-1,3-dienesviathe reaction with aryllithium reagents. Moreover, the vinyl phosphordiamidates were converted into alpha,beta-unsaturated ketones using Grignard reagents. Based on the performed experiments, we proposed a reaction mechanism, which was confirmed by means of the isolation of key intermediates.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/GA18-12150S" target="_blank" >GA18-12150S: Synthesis and characterization of semiconducting supramolecules of novel type and their use in preparation of organic transistors (OFETs)</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
RSC Advances
ISSN
2046-2069
e-ISSN
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Volume of the periodical
10
Issue of the periodical within the volume
58
Country of publishing house
GB - UNITED KINGDOM
Number of pages
12
Pages from-to
35109-35120
UT code for WoS article
000573815400014
EID of the result in the Scopus database
2-s2.0-85092553982