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Formation of trisubstituted buta-1,3-dienes and alpha,beta-unsaturated ketonesviathe reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43921716" target="_blank" >RIV/60461373:22310/20:43921716 - isvavai.cz</a>

  • Result on the web

    <a href="https://pubs.rsc.org/en/content/articlepdf/2020/ra/d0ra07472a" target="_blank" >https://pubs.rsc.org/en/content/articlepdf/2020/ra/d0ra07472a</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d0ra07472a" target="_blank" >10.1039/d0ra07472a</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Formation of trisubstituted buta-1,3-dienes and alpha,beta-unsaturated ketonesviathe reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents

  • Original language description

    We studied the reactions of vinyl phosphates and vinyl phosphordiamidates containing an ester functional group with organometallic reagents. We found that the functionalized vinyl phosphates were smoothly converted into tri- and tetrasubstituted buta-1,3-dienesviathe reaction with aryllithium reagents. Moreover, the vinyl phosphordiamidates were converted into alpha,beta-unsaturated ketones using Grignard reagents. Based on the performed experiments, we proposed a reaction mechanism, which was confirmed by means of the isolation of key intermediates.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

    <a href="/en/project/GA18-12150S" target="_blank" >GA18-12150S: Synthesis and characterization of semiconducting supramolecules of novel type and their use in preparation of organic transistors (OFETs)</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    RSC Advances

  • ISSN

    2046-2069

  • e-ISSN

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    58

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    12

  • Pages from-to

    35109-35120

  • UT code for WoS article

    000573815400014

  • EID of the result in the Scopus database

    2-s2.0-85092553982