Amide Bond Formation via Aerobic Photooxidative Coupling of Aldehydes with Amines Catalyzed by a Riboflavin Derivative

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F21%3A43923619" target="_blank" >RIV/60461373:22310/21:43923619 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22810/21:43923619
Result on the web
<a href="https://pubs.acs.org/doi/abs/10.1021/acs.orglett.1c02391" target="_blank" >https://pubs.acs.org/doi/abs/10.1021/acs.orglett.1c02391</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.orglett.1c02391" target="_blank" >10.1021/acs.orglett.1c02391</a>

Result language
angličtina
Original language name
Amide Bond Formation via Aerobic Photooxidative Coupling of Aldehydes with Amines Catalyzed by a Riboflavin Derivative
Original language description
We report an effective, operationally simple, and environmentally friendly system for the synthesis of tertiary amides by the oxidative coupling of aromatic or aliphatic aldehydes with amines mediated by riboflavin tetraacetate (RFTA), an inexpensive organic photocatalyst, and visible light using oxygen as the sole oxidant. The method is based on the oxidative power of an excited flavin catalyst and the relatively low oxidation potential of the hemiaminal formed by amine to aldehyde addition. © 2021 American Chemical Society.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/GA18-15175S" target="_blank" >GA18-15175S: Oxidative photocatalytic systems with flavinium salts for direct C-H functionalizations</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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