Determination of Diaryliodonium Species by Reverse Iodometric Titration with Ascorbic Acid
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43924275" target="_blank" >RIV/60461373:22310/23:43924275 - isvavai.cz</a>
Result on the web
<a href="https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/elan.202200376" target="_blank" >https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/elan.202200376</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/elan.202200376" target="_blank" >10.1002/elan.202200376</a>
Alternative languages
Result language
angličtina
Original language name
Determination of Diaryliodonium Species by Reverse Iodometric Titration with Ascorbic Acid
Original language description
Diaryliodonium salts are used in organic chemistry, materials science and pharmaceutical chemistry. For the quantitative analysis of diaryliodonium salts, only instrumentally demanding techniques requiring highly skilled operators are available. Surprisingly, no titration method taking advantage of the oxidising ability of diaryliodonium is available in the literature. In the present work, a titration method for the determination of diaryliodonium salts is presented. It is based on the reaction of diaryliodonium species with ascorbic acid, whose excess is subsequently determined by means of iodometric potentiometric titration. Application of the protocol to various diaryliodonium salts revealed the scope and limitations of the method. © 2023 Wiley-VCH GmbH.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry
Result continuities
Project
<a href="/en/project/EF16_025%2F0007445" target="_blank" >EF16_025/0007445: Organic redox couple based batteries for energetics of traditional and renewable resources.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>O - Projekt operacniho programu
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electroanalysis
ISSN
1040-0397
e-ISSN
1521-4109
Volume of the periodical
35
Issue of the periodical within the volume
5
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
nestránkováno
UT code for WoS article
000891971700001
EID of the result in the Scopus database
2-s2.0-85142922087