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Thermodynamic model and surface-active components of barium crystal glass

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43925872" target="_blank" >RIV/60461373:22310/23:43925872 - isvavai.cz</a>

  • Result on the web

    <a href="https://link.springer.com/article/10.1007/s10973-022-11704-x" target="_blank" >https://link.springer.com/article/10.1007/s10973-022-11704-x</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10973-022-11704-x" target="_blank" >10.1007/s10973-022-11704-x</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermodynamic model and surface-active components of barium crystal glass

  • Original language description

    The surface tension of fifteen glass-forming melts was measured by sessile drop profile analysis. The glass compositions were based on barium crystal glass [(10.49 Na2O center dot 2.36 K2O center dot 9.06 CaO center dot 0.78 ZnO center dot 2.44 BaO center dot 0.85 Al2O3 center dot 74.02 SiO2) mol%] and were changed by increasing and decreasing of the each oxide content. The drop profiles were recorded at 1190 degrees C and analyzed by the numerical integration of Laplace&apos;s equation using the experimentally determined melt density. The results show that the increasing content of Na2O, K2O, ZnO, Al2O3 and SiO2 significantly decreases the surface tension. The Shakhmatkin and Vedishcheva thermodynamic model (TDM) was used to describe each glass melt at 1190 degrees C. 57 components were considered in the TDM, but only 25 components were present in non-negligible equilibrium amounts. Multilinear analysis was used to determine the surface-active components, i.e., components that decrease the surface tension. The analysis was performed using the dependence of surface tension on the equilibrium molar amounts of non-negligible and statistically independent components of the TDM.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20504 - Ceramics

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Thermal Analysis and Calorimetry

  • ISSN

    1388-6150

  • e-ISSN

    1588-2926

  • Volume of the periodical

    148

  • Issue of the periodical within the volume

    říjen

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

  • UT code for WoS article

    000871520100001

  • EID of the result in the Scopus database

    2-s2.0-85140358629