BioMOF coupled with plasmonic CuNPs for sustainable CO2 fixation in cyclic carbonates at ambient conditions

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43926152" target="_blank" >RIV/60461373:22310/23:43926152 - isvavai.cz</a>
Alternative codes found
RIV/44555601:13440/23:43897696 RIV/00216208:11320/23:10475230
Result on the web
<a href="https://doi.org/10.1016/j.jcou.2023.102416" target="_blank" >https://doi.org/10.1016/j.jcou.2023.102416</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jcou.2023.102416" target="_blank" >10.1016/j.jcou.2023.102416</a>

Result language
angličtina
Original language name
BioMOF coupled with plasmonic CuNPs for sustainable CO2 fixation in cyclic carbonates at ambient conditions
Original language description
To improve the actual environmental situation, in closing the loop of carbon dioxide (CO2) cycle by reutilization, the CO2 activation is necessary. The energy inputs for that should be economically viable and renewable, while the catalyst(s) should come from naturally abundant elements and building blocks. Important should be also technological simplicity of CO2 activation and environmental friendliness of used chemicals. In this work, we propose a promising solution for CO2 reutilization based on plasmon-assisted photocatalysis using CuNPs and MOF, based on L-glutamic acid and Zn ions (ZnGlu). ZnGlu crystals were hybridized with CuNPs to introduce plasmon-related (photo)absorption bands at visible wavelengths. ZnGlu is responsible for catalytic activity, triggered by the high-energy field of plasmonic dipoles of CuNPs. The proposed catalyst was used for CO2 cycloaddition with different reactivity forming corresponding carbonates and meets the following criteria: catalyst's material-copper, light as a renewable energy source, functionality at normal temperature and pressure.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
20501 - Materials engineering

Project
<a href="/en/project/GA20-01639S" target="_blank" >GA20-01639S: New Generation of Organic/Inorganic Materials for Carbon Dioxide Detection, Capture and Utilization</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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