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Photoinduced CO2 Conversion under Arctic Conditions─The High Potential of Plasmon Chemistry under Low Temperature

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43926961" target="_blank" >RIV/60461373:22310/23:43926961 - isvavai.cz</a>

  • Alternative codes found

    RIV/44555601:13440/23:43897693 RIV/00216275:25310/23:39920540

  • Result on the web

    <a href="https://pubs.acs.org/doi/10.1021/acscatal.2c05891" target="_blank" >https://pubs.acs.org/doi/10.1021/acscatal.2c05891</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acscatal.2c05891" target="_blank" >10.1021/acscatal.2c05891</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Photoinduced CO2 Conversion under Arctic Conditions─The High Potential of Plasmon Chemistry under Low Temperature

  • Original language description

    The conversion of CO2 to fine chemicals is an efficient tool for reducing the negative impact of human activities on the environment. In this work, we show that CO2 capture and its sunlight-based activation can proceed efficiently even at low, practically arctic temperatures with the implementation of so-called plasmon-assisted chemistry. We propose the specific photocatalyst consisting of two parts: (i) an organic shell responsible for CO2 capture and (ii) a plasmon-active metal nanoparticle core for activation of entrapped CO2 and involving it in the cycloaddition reaction. The effect of temperature on the plasmon-assisted CO2 cycloaddition was studied, and a reaction with only slight temperature sensitivity was observed. Theoretical calculations indicated a significant decrease in the “apparent” activation barrier of the reaction under the plasmon-assisted mechanism. Our results open an opportunity for the world economy to exploit the vast Arctic and Antarctic (or close to them) territories where the powerful solar potential is practically not used yet. © 2023 The Authors. Published by American Chemical Society.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

    <a href="/en/project/GA22-02022S" target="_blank" >GA22-02022S: Hybrid materials and advanced structures for mimicking natural photosynthesis</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS Catalysis

  • ISSN

    2155-5435

  • e-ISSN

  • Volume of the periodical

    13

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    3830-3840

  • UT code for WoS article

    000951498200001

  • EID of the result in the Scopus database

    2-s2.0-85149459420