Site Selective Concerted Nucleophilic Aromatic Substitutions of Azole-Ligated Diaryliodonium Salts

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43934051" target="_blank" >RIV/60461373:22310/23:43934051 - isvavai.cz</a>

Result on the web

<a href="https://doi.org/10.1002/adsc.202201001" target="_blank" >https://doi.org/10.1002/adsc.202201001</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/adsc.202201001" target="_blank" >10.1002/adsc.202201001</a>

Result language

angličtina

Original language name

Site Selective Concerted Nucleophilic Aromatic Substitutions of Azole-Ligated Diaryliodonium Salts

Original language description

Diaryliodonium salts are electrophilic arylation reagents in transition metal-catalyzed and transition metal-free reaction methods. Herein we present the application of azole-stabilized diaryliodonium salts with additional thiophene-2-yl-ligands as substrates for metal-free nucleophilic arylations. Besides their synthesis, we demonstrate their application in chemoselective nitrations, oxygenations, aminations as well as thiolations under umpolung conditions. Convenient one-pot procedures based on their in situ formation are also discussed. (Figure presented.). © 2023 The Authors. Advanced Synthesis &amp; Catalysis published by Wiley-VCH GmbH.

Czech name

—

Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10401 - Organic chemistry

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2023

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

ADVANCED SYNTHESIS &amp; CATALYSIS

ISSN

1615-4150

e-ISSN

—

Volume of the periodical

365

Issue of the periodical within the volume

4

Country of publishing house

DE - GERMANY

Number of pages

9

Pages from-to

535-543

UT code for WoS article

000926078000001

EID of the result in the Scopus database

2-s2.0-85147185689