Modular assembly of a library of hybrid superlattices and artificial quantum solids
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F24%3A43929954" target="_blank" >RIV/60461373:22310/24:43929954 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/abs/pii/S2590238523006422" target="_blank" >https://www.sciencedirect.com/science/article/abs/pii/S2590238523006422</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.matt.2023.12.029" target="_blank" >10.1016/j.matt.2023.12.029</a>
Alternative languages
Result language
angličtina
Original language name
Modular assembly of a library of hybrid superlattices and artificial quantum solids
Original language description
Hybrid superlattices, composed of two-dimensional atomic crystals (2DACs) and self -assembled molecular layers, provide a platform for synergizing the rich physical properties of solid-state 2DACs with customizable molecular functionalities. This study introduces a modular electrostatic co -assembly approach for synthesizing 53 distinct hybrid superlattices, using various 2DACs and molecular building blocks. Mechanistic studies reveal that the electrostatic assembly is governed by charge balance and the equilibrium between electrostatic and van der Waals interactions. Leveraging the charge balance principle, we demonstrate a precise control over the number of molecular layers and interlayer spacing by modulating the molecular charge density. Our study establishes a universal approach to a library of layered hybrid superlattices, incorporating versatile molecular functionalities into solid-state 2DACs. It promises a novel class of artificial quantum solids with designable electronic band offsets, tailored charge ordering, superconducting phase transitions, and magnetic ordering.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Matter
ISSN
2590-2393
e-ISSN
2590-2385
Volume of the periodical
7
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
16
Pages from-to
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UT code for WoS article
001203011700001
EID of the result in the Scopus database
2-s2.0-85184774385