Inhibiting effects during the co-conversion of lauric acid and anisole over Ni and NiMo catalysts
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F24%3A43930037" target="_blank" >RIV/60461373:22310/24:43930037 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22320/24:43930037 RIV/60461373:22350/24:43930037
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0926860X24001224?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0926860X24001224?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.apcata.2024.119889" target="_blank" >10.1016/j.apcata.2024.119889</a>
Alternative languages
Result language
angličtina
Original language name
Inhibiting effects during the co-conversion of lauric acid and anisole over Ni and NiMo catalysts
Original language description
The co-hydroconversion of lauric acid and anisole was carried out over Ni and NiMo catalysts T=260 and 280 degrees C and pH2=40 bar. Ni/Al2O3 demonstrated a high activity in converting anisole to cyclohexane, but lauric acid conversion was suppressed over this catalyst. In the co-conversion of their mixture the phenolic had no effect on the conversion of the acid, but the latter prevented the cleavage of the C-O bond in both anisole and reaction intermediates. It was assumed that the successful conversion of anisole in its mixture with lauric acid required that a catalyst should provide the fast consumption of the acid component. Accordingly, NiMo/Al2O3 possessed a high activity in lauric acid conversion, and a high cyclohexane yield from anisole was observed after the complete consumption of the acid. The results of the present study can be useful for the rational design of a catalyst for the effective hydroconversion of bio-oil.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20704 - Energy and fuels
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
APPLIED CATALYSIS A-GENERAL
ISSN
0926-860X
e-ISSN
1873-3875
Volume of the periodical
685
Issue of the periodical within the volume
Březen 2024
Country of publishing house
ZA - SOUTH AFRICA
Number of pages
15
Pages from-to
119889
UT code for WoS article
001275722300001
EID of the result in the Scopus database
2-s2.0-85199064121