Thermodynamic Study of N-Methylformamide and N,N-Dimethyl-Formamide
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F24%3A43930279" target="_blank" >RIV/60461373:22310/24:43930279 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/24:43930279
Result on the web
<a href="https://www.mdpi.com/1420-3049/29/5/1110" target="_blank" >https://www.mdpi.com/1420-3049/29/5/1110</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/molecules29051110" target="_blank" >10.3390/molecules29051110</a>
Alternative languages
Result language
angličtina
Original language name
Thermodynamic Study of N-Methylformamide and N,N-Dimethyl-Formamide
Original language description
An extensive thermodynamic study of N-methylformamide (CAS RN: 123-39-7) and N,N-dimethylformamide (CAS RN: 68-12-2), is presented in this work. The liquid heat capacities of N-methylformamide were measured by Tian-Calvet calorimetry in the temperature interval (250-300) K. The vapor pressures for N-methylformamide and N,N-dimethylformamide were measured using static method in the temperature range 238 K to 308 K. The ideal-gas thermodynamic properties were calculated using a combination of the density functional theory (DFT) and statistical thermodynamics. A consistent thermodynamic description was developed using the method of simultaneous correlation, where the experimental and selected literature data for vapor pressures, vaporization enthalpies, and liquid phase heat capacities and the calculated ideal-gas heat capacities were treated together to ensure overall thermodynamic consistency of the results. The resulting vapor pressure equation is valid from the triple point to the normal boiling point temperature.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GA22-07164S" target="_blank" >GA22-07164S: Rational design of drug delivery systems based on tailored biodegradable polymers using an iterative in silico and experimental approach</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
MOLECULES
ISSN
1420-3049
e-ISSN
1420-3049
Volume of the periodical
29
Issue of the periodical within the volume
5
Country of publishing house
CH - SWITZERLAND
Number of pages
20
Pages from-to
1110
UT code for WoS article
001183384300001
EID of the result in the Scopus database
2-s2.0-85187893702