Vapor Pressures and Thermophysical Properties of Dimethyl Carbonate, Diethyl Carbonate, and Dipropyl Carbonate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F17%3A43913244" target="_blank" >RIV/60461373:22340/17:43913244 - isvavai.cz</a>
Result on the web
<a href="http://pubs.acs.org/doi/abs/10.1021/acs.jced.7b00295" target="_blank" >http://pubs.acs.org/doi/abs/10.1021/acs.jced.7b00295</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jced.7b00295" target="_blank" >10.1021/acs.jced.7b00295</a>
Alternative languages
Result language
angličtina
Original language name
Vapor Pressures and Thermophysical Properties of Dimethyl Carbonate, Diethyl Carbonate, and Dipropyl Carbonate
Original language description
In this work, a thermodynamic study of important industrial solvents, dimethyl carbonate (CAS RN: 616-38-6), diethyl carbonate (CAS RN: 105-58-8), and dipropyl carbonate (CAS RN: 623-96-1), is presented. The vapor pressure measurements were performed using the static method in the temperature interval 238?308 K. Heat capacities of condensed phases were measured by Tian?Calvet calorimetry in the temperature interval 260?358 K. The phase behavior was investigated by DSC in the temperature interval 183?300 K. The thermodynamic properties in the ideal gaseous state were calculated using the methods of statistical thermodynamics based on calculated fundamental vibrational frequencies and molecular structure data. Calculated ideal-gas heat capacities and experimental data on vapor pressures, condensed phase heat capacities, and vaporization enthalpies were treated simultaneously to obtain a consistent thermodynamic description.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GA17-03875S" target="_blank" >GA17-03875S: Theoretical and experimental study of thermodynamic properties and phase behavior of molecular crystals</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Engineering Data
ISSN
0021-9568
e-ISSN
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Volume of the periodical
62
Issue of the periodical within the volume
10
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
"3206 "- 3215
UT code for WoS article
000413131800021
EID of the result in the Scopus database
2-s2.0-85031327650