Boosting the Ni-Catalyzed Hydrodeoxygenation (HDO) of Anisole Using Scrap Catalytic Converters
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22320%2F22%3A43924577" target="_blank" >RIV/60461373:22320/22:43924577 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22350/22:43924577
Result on the web
<a href="http://https:dx.doi.org10.1002/adsu.202100394" target="_blank" >http://https:dx.doi.org10.1002/adsu.202100394</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adsu.202100394" target="_blank" >10.1002/adsu.202100394</a>
Alternative languages
Result language
angličtina
Original language name
Boosting the Ni-Catalyzed Hydrodeoxygenation (HDO) of Anisole Using Scrap Catalytic Converters
Original language description
The large availability and renewable nature of lignin makes its upgrading to bioproducts of particular interest for sustainable development. The hydrodeoxygenation (HDO) of anisole specifically represents a model reaction for the conversion of lignin to biofuels through the removal of the aromatic carbon-oxygen bonds. To date, a range of Ni-based catalysts have been reported as highly active systems for the HDO of anisole. However, there has been a substantial lack of consideration given to the environmental characteristics of these catalytic systems, in contrast with the scope of the sustainable production of biofuels. Herein, Ni-based SiO2 catalysts are prepared by a solventless and highly efficient mechanochemistry approach, having a considerably lower environmental impact as compared to standard impregnation methods. Importantly, scrap catalytic converters (SCATs) are employed as co-catalysts, proving the possibility of enhancing the catalytic HDO of anisole, with a scarcely exploited waste material. The results demonstrate that the combined use of Ni/SiO2 as catalysts and Ni/SCATs as co-catalysts remarkably boosts the rate of the conversion of anisole up to more than 50% by achieving an almost complete conversion of anisole in only 40 min instead of at 200 °C and 4 MPa H2. © 2022 The Authors. Advanced Sustainable Systems published by Wiley-VCH GmbH.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20704 - Energy and fuels
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Advanced Sustainable Systems
ISSN
2366-7486
e-ISSN
2366-7486
Volume of the periodical
6
Issue of the periodical within the volume
4
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
nestrankovano
UT code for WoS article
000769481200001
EID of the result in the Scopus database
2-s2.0-85126296181