Regio- and stereoselective C-H functionalization of brassinosteroids
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22330%2F19%3A43917976" target="_blank" >RIV/60461373:22330/19:43917976 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0039128X19300613?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0039128X19300613?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.steroids.2019.03.010" target="_blank" >10.1016/j.steroids.2019.03.010</a>
Alternative languages
Result language
angličtina
Original language name
Regio- and stereoselective C-H functionalization of brassinosteroids
Original language description
Late stage C-H functionalization is a powerful tool for modification of natural compounds. Herein we report that the rhodium-catalyzed reaction of brassinosteroids with aryloxysulfonamides proceeds regio- and stereoselectively at C15 position. The derivative obtained from 24-epibrassinolide was easily transformed to the conjugate with a BODIPY dye bearing unaffected functional groups of the native brassinosteroid.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Steroids
ISSN
0039-128X
e-ISSN
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Volume of the periodical
146
Issue of the periodical within the volume
06.2019
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
92-98
UT code for WoS article
000467508700011
EID of the result in the Scopus database
2-s2.0-85063960661